紫外线吸收剂 |
添加时间:2018/3/24 15:36:48 浏览次数: |
紫外线吸收剂是一种光稳定剂,能吸收阳光及荧光光源中的紫外线部分,而本身又不发生变化。塑料和其他高分子材料在日光和荧光下,因紫外线的作用,产生自动氧化反应,导致聚合物的降解而劣化,使外观及机械性能变坏。加入紫外线吸收剂后可选择性地吸收这种高能量的紫外线,使之变成无害的能量而释放或消耗。由于聚合物的种类不同,使其劣化的紫外线波长也不相同,不同的紫外线吸收剂可吸收不同波长的紫外线,使用时,应根据聚合物的种类选择紫外线吸收剂。
The ultraviolet absorber is a light stabilizer that absorbs the ultraviolet part of the sunlight and the fluorescent light source, and does not change itself. Plastics and other polymer materials produce automatic oxidation reaction under UV and sunlight, resulting in degradation and deterioration of polymers, resulting in deterioration of appearance and mechanical properties. After adding ultraviolet absorbents, this high energy ultraviolet ray can be selectively absorbed to make it become harmless energy and release or consume. Due to the different kinds of polymers, the UV wavelengths of their degradation are also different. Different ultraviolet absorbers can absorb different wavelengths of ultraviolet. When applied, UV absorbers should be selected according to the type of polymer.
紫外线吸收剂应该具备以下条件:①可强烈地吸收紫外线(尤其是波长为290-400nm);②热稳定性好,即使在加工中也不会因热而变化,热挥发性小;③化学稳定性好,不与制品中材料组分发生不利反应;④混溶性好,可均匀地分散在材料中,不喷霜,不渗出;⑤吸收剂本身的光化学稳定性好,不分解,不变色;⑥无色、无毒、无臭;⑦耐浸洗;⑧价廉、易得;⑨不溶,或难溶于水。
The ultraviolet absorbent should meet the following conditions: 1 can strongly absorb ultraviolet light (especially wavelength 290-400nm); second, good thermal stability, but also will not change due to heat even in the machining process, the heat of low volatility and good chemical stability; and the products of material components occurred adverse reaction; the good miscibility. Can be uniformly dispersed in the material, no blooming, no exudation; the absorbent itself good photochemical stability, does not decompose, do not change color; the colorless, non-toxic, odorless and resistant; immersion; the cheap and easy to get; we do not dissolve, or difficult to dissolve in water.
紫外线吸收剂用于塑料、涂料、染料、汽车挡风玻璃、化妆品、药物、防晒剂等。
UV absorbers are used in plastics, coatings, dyes, car windshield, cosmetics, drugs, sunscreen and so on.
三.分类:
Three. Classification:
紫外线吸收剂按化学结构可分为以下几类:水杨酸酯类、苯酮类、苯并三唑类、取代丙烯腈类、三嗪类和其他类。以下是几种常见的紫外线吸收剂简介。
UV absorbers can be divided into the following categories according to their chemical structure: salicylate, benzophenone, benzo three azole, substituted acrylonitrile, three azine and other classes. The following are several common introduction of ultraviolet absorbents.
商品名 水杨酯苯酯
Salicylate benzyl ester
成 分 邻羟基苯甲酸苯酯
Benzoate phthalate
性能及用途 无色结晶粉末。具有令人愉快的芳香气味(冬青油气味)。密度1.250g/cm3,溶点43,沸点(1.6kPa)173。易溶于乙醚、苯和氯仿,溶于乙醇,几乎不溶于水和甘油。含量99%。
Performance and use of colorless crystalline powder. It has a pleasant aroma (odour of Holly oil). The density of 1.250g/cm3 43, melting point, boiling point (1.6kPa) 173. Soluble in ether, benzene and chloroform, soluble in ethanol, almost insoluble in water and glycerin. The content is 99%.
本品为一种紫外线吸收剂,用于塑料制品,但吸收波长范围较窄。美国食品药物管理局批准用于接触食品的丙烯酸树脂用品。
This product is a kind of ultraviolet absorbent, used in plastic products, but the absorption wavelength range is narrow. The food and Drug Administration of the United States approved acrylic resin supplies for contact with food.
包装及贮运 纸桶内衬塑料袋包装。按一般化学品规定贮运。
Packaging and storage drum lined with plastic bags. Storage and transportation according to the regulations of the general chemicals.
商品名 紫外线吸收剂UV-O
Product name UV absorber UV-O
成 分 2,4-二羟基二苯甲酮
Component 2, 4- two hydroxyl two Benzophenone
性能及用途 本品为淡色针状结晶或白色粉末。水分<0.5%。灰分<0.5%。熔点136~149℃。溶于丙酮、甲醇、乙醇、甲乙酮、二恶烷、N-甲基吡啶酮和醋酸乙酯,极难溶于水,正庚烷和苯。本品在部分溶剂中的溶解度(g/100ml溶剂,25℃)丙酮50,苯1,乙醇>50,水<0.5,正庚烷<0.5。
The performance and use of this product is light colored needle crystalline or white powder. The water is less than 0.5%. The ash is less than 0.5%. The melting point is 136~149 degrees centigrade. Soluble in acetone, methanol, ethanol, methyl ethyl ketone, two oxane, N- methylpyridone and ethyl acetate, which are extremely difficult to dissolve in water, n-heptane and benzene. The solubility of this product in some solvents (g/100ml solvent, 25 C) acetone 50, benzene 1, ethanol > 50, water < 0.5, n-heptane < 0.5.
本品为紫外线吸收剂,适用于聚氯乙烯、聚苯乙烯、环氧树脂、纤维素树脂、不饱和聚酯、涂料和合成橡胶等。最大吸收波长范围280~340nm,一般用量0.1%1%。但本品的光稳定效果并不突出。
This product is a UV absorber. It is suitable for polyvinyl chloride, polystyrene, epoxy resin, cellulose resin, unsaturated polyester, coating and synthetic rubber. The maximum absorption wavelength range is 280 ~ 340nm, and the average amount is 0.1%1%. But the light stabilization effect of this product is not outstanding. |
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